WAEC 2019 Chemistry Obj And Essay Answer – May/June Expo

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KEEP REFRESHING IN EVERY 5MIN 
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Chemistry OBJ:
1DAABADACBD
11AABCACDADD
21CCABBDDBAA
31AABDBCDBCB
41BACBCCBDDD

(1a)
-High temperature is required 
-High pressure 
-The presence of Catalyst 

(1b)
(i) To avoid corrosion
(ii) To avoid rusting

(1ci)
Calcium oxide (CaO)  is alkaline and Hcl is acidic. The two react to form calcium chloride and water; instead of dry Hcl, after that, it will end up with wet calcium chloride.

(1cii)
Concentrated H2SO4(aq)

(1d)
Conc HNO#(aq) reacts with a solution of FeSO4(aq). The Fe2+ was oxidised to yellow Fe3+ and brown NO2(g) was given off.
ie 2HNO3(aq) + 2FeSO4(aq) + H2SO4 -> Fe2(SO4)3 + 2NO2(g) + 2H2O

(1ei)
(I) ZnO(s) + H2SO4(aq) ---> ZnSO4(aq) + H2O(l) 
(II) ZnO(s) + NaOH(aq) ---> Na2ZnO2(s) + H2O(l)

(1eii)
(III) Amphoteric property

(1f) 
(i) They have the same number of atoms 
(ii) They have different neutron number which makes their mass number to differ

(1g) 
HclO - Oxochlorate(i)acid and Hcl

(1hi) 
H2S is undergoing oxidation to S(s)

(1hii) 
SO2

(1i)
Carbon-12 scale is the standard from which atomiv masses of all nucleids are measured. It is used to ascertain mole of a substance as the amount of substance which contains as many elementry entities as there are atoms in 12 grams of carbon-12. 

(1j)
(i) The concentration of thereactants and products are equal
(ii) The rate of the forward reaction is same as rate of the backward reaction
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(2ai)
C10H22----->(cracking)---->C6H14 + C4H8
P is C4H8
(2aii)
H H H H
| | | |
H-C=C-C-C-H
| |
H H
H CH3 H
| | |
H-C= C- C-H
|
H
(2aiii)
P would be polymerized because it contain double bond
(2b)
Hundi's rule: Electrons occupy each orbital singly first before pairing takes place in a degenerated orbital
Aufbau's principle: Electrons enter into orbitals in order of increasing energy
(2ci)
- NaH ---> ionic
- H2 --> Covalent
- H2S --> Covalent
- NH4Cl -- Vander waals
(2cii)
- NaH ---> soluble (dissolve)
- H2 --> Insoluble
- H2S --> Moderately soluble
- NH4Cl -- soluble
(2ciii)
- H2S(g) + H2O(l) ---> H3O^+(aq) + HS(aq)
- HS(aq) + H2O(l) ---> H3O^+(aq) + S^2-(aq)
(2d)
(i)Number of unpaired electrons=zero
(ii)J would be a good reducing agent
(iii)It is found in group 2. It is a metal. Metals are good reducing agent
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(5ai)
DRAW THE DIAGRAM: CLICK HERE FOR THE IMAGE
(5aii)
(i)It is used in the sterilization of water for domestic and industrial use and in the treatment of sewage
(ii)It is used as a bleaching agent for cotton linen and wood-pulp
(5b)
Preparation of hydrogen from water gas:
This is called Bosch process: In this process large quantities of hydrogen are produced from cheap raw materials namely water and coke when steam is passed over red hot coke (carbon) at about 1200C, a mixture of carbon(II) oxide and hydrogen ion and water gas is produced .Excess steam is then mixed with the water gas and passed over a catalyst iron(III)oxide at 450C.As a result the carbon(II)oxide in the water gas is converted by CO2 with a further yield of hydrogen
Endothermic reaction
H2O(g) + C(s)---> CO(g)
(5ci)
The chief ore of aluminium is bauxite
(5cii)
The ore of aluminium is purified by electrolysis to remove the impurities present
(5ciii)
Carbon or platinum electrodes
(5civ)
Cryolite is added to remove the impurities present
(5d)
Coal, coal tar, ammoniacal liquor

COMPLETED

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